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原子层沉积 2

合成橡胶 2

地震预测 2

汶川地震 2

湍流边界层 2

直接数值模拟 2

相干结构 2

(GaxIn1−x)2O3薄膜；带隙可调谐；磁控溅射 1

3D支架平台 1

4D打印 1

5G 1

WTO 1

ZN-1阻尼橡胶材料 1

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Parametric study on seismic performance of self-centering reinforced concrete column with bottom-placed rubberlayer

《结构与土木工程前沿（英文）》页码 1145-1162 doi: 10.1007/s11709-023-0945-2

摘要： To realize seismic-resilient reinforced concrete (RC) moment-resisting frame structures, a novel self-centering RC column with a rubber layer placed at the bottom (SRRC column) is proposed herein. For the column, the longitudinal reinforcement dissipates seismic energy, the rubber layer allows the rocking of the column, and the unbonded prestressed tendon enables self-centering capacity. A refined finite element model of the SRRC column is developed, the effectiveness of which is validated based on experimental results. Results show that the SRRC column exhibits stable energy dissipation capacity and no strength degradation; additionally, it can significantly reduce permanent residual deformation and mitigate damage to concrete. Extensive parametric studies pertaining to SRRC columns have been conducted to investigate the critical factors affecting their seismic performance.

关键词： seismic resilience self-centering rubber layer flag-shaped hysteresis loop parametric study

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Evaluation of the compatibility between rubber and asphalt based on molecular dynamics simulation

Fucheng GUO, Jiupeng ZHANG, Jianzhong PEI, Weisi MA, Zhuang HU, Yongsheng GUAN

《结构与土木工程前沿（英文）》 2020年第14卷第2期页码 435-445 doi: 10.1007/s11709-019-0603-x

摘要： Using of rubber asphalt can both promote the recycling of waste tires and improve the performance of asphalt pavement. However, the segregation of rubber asphalt caused by the poor storage stability always appears during its application. Storage stability of asphalt and rubber is related to the compatibility and also influenced by rubber content. In this study, molecular models of different rubbers and chemical fractions of asphalt were built to perform the molecular dynamics simulation. The solubility parameter and binding energy between rubber and asphalt were obtained to evaluate the compatibility between rubber and asphalt as well as the influence of rubber content on compatibility. Results show that all three kinds of rubber are commendably compatible with asphalt, where the compatibility between asphalt and cis-polybutadiene rubber (BR) is the best, followed by styrene-butadiene rubber (SBR), and natural rubber (NR) is the worst. The optimum rubber contents for BR asphalt, SBR asphalt, and NR asphalt were determined as 15%, 15%, and 20%, respectively. In addition, the upper limits of rubber contents were found as between 25% and 30%, between 20% and 25%, and between 25% and 30%, respectively.

关键词： rubber asphalt compatibility rubber content molecular dynamics simulation

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Using thermodynamic parameters to study self-healing and interface properties of crumb rubber modified

Dongliang HU, Jianzhong PEI, Rui LI, Jiupeng ZHANG, Yanshun JIA, Zepeng FAN

《结构与土木工程前沿（英文）》 2020年第14卷第1期页码 109-122 doi: 10.1007/s11709-019-0579-6

摘要： The thermodynamic property of asphalt binder is changed by the addition of crumb rubber, which in turn influences the self-healing property as well as the cohesion and adhesion within the asphalt-aggregate system. This study investigated the self-healing and interface properties of crumb rubber modified asphalt (CRMA) using thermodynamic parameters based on the molecular simulation approach. The molecular models of CRMA were built with representative structures of the virgin asphalt and the crumb rubber. The aggregate was represented by SiO and Al O crystals. The self-healing capability was evaluated with the thermodynamic parameter wetting time, work of cohesion and diffusivity. The interface properties were evaluated by characterizing the adhesion capability, the debonding potential and the moisture susceptibility of the asphalt-aggregate interface. The self-healing capability of CRMA is found to decrease as the rubber content increases. The asphalt-Al O interface with higher rubber content has stronger adhesion and moisture stability. But the influence of crumb rubber on the interfacial properties of asphalt-SiO interface has no statistical significance. Comparing with the interfacial properties of the asphalt-SiO interface, the asphalt-Al O interface is found to have a stronger adhesion but a worse moisture susceptibility for its enormous thermodynamic potential for water to displace the asphalt binder.

关键词： crumb rubber modified asphalt surface free energy self-healing interface properties molecular dynamics simulation

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溶液聚合合成橡胶节能技术和节能型橡胶的开发

曹湘洪,张爱民

《中国工程科学》 2001年第3卷第7期页码 59-63

摘要：

总结了燕山石化溶液聚合合成橡胶节能技术和节能型橡胶的开发情况。通过改进催化体系，提高反应速度，提高反应器的生产能力，并在聚合反应器中采用带刮刀的搅拌器，同时改进聚合、凝聚、溶剂回收的部分工艺及设备，燕山石化顺丁橡胶的能耗不断下降，达到世界先进水平。溶液聚合合成橡胶凝聚过程热泵技术的工业化，使生产每吨胶可节约1MPa的低压蒸汽0.72t。橡胶溶液直接脱挥，聚丁二烯橡胶气相聚合工艺技术开发,溶聚丁苯橡胶（SSBR）、中乙烯基聚丁二烯橡胶、苯乙烯-异戊二烯-丁二烯橡胶（SIBR）、苯乙烯-丁二烯热塑性弹性体（SBS）等新型节能型合成橡胶的技术开发也在进行中，其中SSBR、SBS技术已经工业化。

关键词：溶液聚合合成橡胶节能节能型橡胶

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Aging properties and aging mechanism of activated waste rubber powder modified asphalt binder based on

《结构与土木工程前沿（英文）》 2023年第17卷第4期页码 625-636 doi: 10.1007/s11709-023-0938-1

摘要： The research and development of high-performance pavement materials has been intensified owing to the demand for long-life pavements. This study is performed to develop a novel pavement material using waste rubber powder, waste lubricating by-product (LBP), and asphalt. Subsequently, the aging properties and aging mechanism of activated waste rubber powder modified asphalt (ARMA) are investigated based on its rheological properties and micro-characterization. The rheological results show that, compared with waste rubber powder modified asphalt (RMA), ARMA offers a higher aging resistance and a longer fatigue life. A comparison and analysis of the rheological aging parameters of ARMA and RMA show that LBP activation diminishes the aging sensitivity of ARMA. The micro-characterization result shows that the aging of ARMA may be caused by the fact that LBP-activated waste rubber powder is more reactive and can form a dense colloidal structure with asphalt. Therefore, the evaporation loss of asphalt light components by heat and the damage to the colloidal structure by oxygen during the aging process are impeded, and the thermal-oxidative aging resistance of ARMA is improved.

关键词： rubber powder modified asphalt aging mechanism rheological characterization

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Relationship between the number of tapping-induced secondary laticifer lines and rubber yield among

Yueyi CHEN,Xinsheng GAO,Xiaofei ZHANG,Weimin TIAN

《农业科学与工程前沿（英文）》 2016年第3卷第4期页码 363-367 doi: 10.15302/J-FASE-2016122

摘要： The lack of suitable early selection parameters means that traditional rubber breeding for yield is time-consuming and inefficient. Laticifer is a tissue specific for natural rubber biosynthesis and storage in rubber tree. The number of the secondary laticifers in the trunk bark tissues is positively correlated with rubber yield in the matured rubber trees that are regularly tapped. In the present study, the rubber yield from 280 of 4–5 year-old virgin trees from 7 cross combinations was compared with the number of newly differentiated secondary laticifers caused by tapping. Results showed that the number of tapping-induced lines of secondary laticifers varied in different germplasm and was positively related to the rubber yield, indicating this could be used as a suitable parameter for early evaluation of yield potential of rubber trees.

关键词： Hevea brasiliensis rubber yield breeding early evaluation tapping secondary laticifer differentiation

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Study on the gas permeabilities in styrene-butadiene rubber by molecular dynamics simulation

Hailu LIU, Xuejia DING, Jun YI, Liqun ZHANG, Sizhu WU,

《化学科学与工程前沿（英文）》 2010年第4卷第3期页码 257-262 doi: 10.1007/s11705-009-0270-x

摘要： In this research, molecular dynamics (MD)simulations were used to study the transport properties of small gas molecules in the butadiene-styrene copolymer(SBR). The condensed-phase optimized molecular potentials for atomistic simulation studies (COMPASS) force field was applied. The diffusion coefficients were obtained from MD (NVT ensemble) and the relationship between gas permeability; the chemical structure and free volume of butadiene-styrene copolymer were investigated. The results indicated that the diffusion coefficient of oxygen declined with increasing styrene content. The fraction of free volume (FFV) in butadiene-styrene copolymer was calculated. It was concluded that diffusion coefficient increased as the FFV increases, which is in accordance with the analysis of the small molecular hop through the free volume in polymer matrix. Subsequently, the glass transition temperatures of these copolymers were calculated by MD. The result showed that the glass transition temperature increased with increasing styrene content in polymer.

关键词： diffusion atomistic simulation permeability chemical structure relationship

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合成橡胶化学及技术进展

武冠英

《中国工程科学》 1999年第1卷第3期页码 79-85

摘要：

文章从合成橡胶的化学基础出发，叙述了合成橡胶工业二十世纪以来的过去、现状，并展望未来。着重讨论了合成化学基础及相应聚合工艺过程的进步这两方面的问题。指出合成橡胶化学基础中活性聚合、可控聚合，包括茂金属催化剂仍为近期的重点；气相聚合工艺将会得到较大的发展；高效聚合釜的研究仍是核心问题；环保问题应更受到重视。

关键词：合成橡胶合成化学活性/控制聚合气相聚合

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The secondary laticifer differentiation in rubber tree is induced by trichostatin A, an inhibitor of

Shixin ZHANG,Shaohua WU,Weimin TIAN

《农业科学与工程前沿（英文）》 2016年第3卷第4期页码 357-362 doi: 10.15302/J-FASE-2016125

摘要： The secondary laticifer, a specific tissue in the secondary phloem of rubber tree, is differentiated from the vascular cambia. The number of the secondary laticifer in the trunk bark of rubber tree is positively correlated with rubber yield. Although jasmonates have been demonstrated to be crucial in the regulation of secondary laticifer differentiation, the mechanism for the jasmonate-induced secondary laticifer differentiation remains to be elucidated. By using an experimental morphological technique, the present study revealed that trichostatin A (TSA), an inhibitor of histone deacetylation, could induce the secondary laticifer differentiation in a concentration-dependent manner. The results suggest that histone acetylation is essential for the secondary laticifer differentiation in rubber tree.

关键词： Hevea brasiliensis histone acetylation laticifer differentiation trichostatin vascular cambia

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我国天然橡胶业面临的挑战和发展战略

黄宗道

《中国工程科学》 2001年第3卷第2期页码 28-32

摘要：

自1949年中华人民共和国建立以来，中国的天然橡胶获得了迅速的发展。到1998年橡胶种植面积达到60×10⁴hm²，是1949前的215倍；产量达到45×10⁴t，是以前的2 250倍。致使中国成为世界天然橡胶的主要产胶国之一，植胶面积为世界第四位，产量为第五位。

我国加人世界贸易组织后，低价的天然橡胶将很快进入我国市场，冲击我国的天然橡胶业，我们必须清醒地了解我们现在所处的地位和情况及时采取对策。文中提出了我国天然橡胶今后的发展战略。

关键词：天然橡胶 WTO 割胶制度

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我国高性能合成橡胶材料发展现状与展望

徐林,曾本忠,王超,张付宝

《中国工程科学》 2020年第22卷第5期页码 128-136 doi: 10.15302/J-SSCAE-2020.05.012

摘要：

合成橡胶材料广泛应用于工业、国防、交通及日常生活的各个方面，高性能和功能化通用合成橡胶是新时代发展所必需的关键先进基础材料。本文结合产业数据调研结果，系统梳理了我国高性能合成橡胶材料的发展现状，总结了我国高性能合成橡胶材料在生产、研发、应用等方面的主要问题。在此基础上提出了我国高性能合成橡胶材料的发展方向与建议，研究认为应重点发展官能化溶聚丁苯橡胶、钕系顺丁橡胶、星型卤化丁基橡胶、功能化热塑性弹性体等高性能和功能化通用合成橡胶，以及氢化丁腈橡胶、热塑性硫化橡胶、高性能硅橡胶、氟醚橡胶等特种橡胶产品，实现材料高端化、过程绿色化、生产智能化。

关键词：合成橡胶，热塑性弹性体，特种橡胶，发展战略

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基于三参量流变模型的止水橡皮粘弹性研究

刘礼华,熊威,张宏志,张清江

《中国工程科学》 2007年第9卷第8期页码 69-71

摘要：

给出了用三参量流变模型研究止水橡胶粘弹性的基本表达式。结合某高水头闸门止水材料的粘弹性试验，得到了所采用橡胶材料的流变参数，并指出了其蠕变变形和应力松弛变化的规律，为工程设计提供参考依据。

关键词：高水头闸门橡胶粘弹性流变

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Chemically reactive solute transfer in a boundary layer slip flow along a stretching cylinder

Swati Mukhopadhyay

《化学科学与工程前沿（英文）》 2011年第5卷第3期页码 385-391 doi: 10.1007/s11705-011-1101-4

摘要： This paper presents the distribution of a solute undergoing a first order chemical reaction in an axisymmetric laminar boundary layer flow along a stretching cylinder. Velocity slip condition at the boundary is used instead of no-slip condition. Similarity transformations are used to convert the partial differential equations corresponding to momentum and concentration into highly nonlinear ordinary differential equations. Numerical solutions of these equations are obtained by the shooting method. The velocity decreases with increasing slip parameter. The skin friction as well as the mass transfer rate at the surface is larger for a cylinder than for a flat plate.

关键词： boundary layer stretching cylinder partial slip mass transfer similarity solution

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ZN － 1阻尼橡胶材料的老化机理研究

张凯,马艳,谭云,梅军

《中国工程科学》 2009年第11卷第2期页码 48-52

摘要：

采用加速老化试验方法对ZN－１阻尼橡胶材料的热氧老化性能进行了研究，获得了不同老化温度及老化时间对硅橡胶泡沫材料力学性能及阻尼性能的影响规律。研究结果表明，随着老化温度的升高及老化时间的延长， ZN－１的拉伸强度出现了先下降后升高的现象，而扯断伸长率则表现为单调下降的趋势。同时，还研究了ZN－１阻尼橡胶材料在热氧老化条件下微观结构与性能变化之间的关系，得到了ZN－１阻尼橡胶材料的热老化机理。

关键词： ZN-1阻尼橡胶材料老化性能微观结构老化机理

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Modeling nanostructured catalyst layer in PEMFC and catalyst utilization

Jiejing ZHANG, Pengzhen CAO, Li XU, Yuxin WANG

《化学科学与工程前沿（英文）》 2011年第5卷第3期页码 297-302 doi: 10.1007/s11705-011-1201-1

摘要： A lattice model of the nanoscaled catalyst layer structure in proton exchange membrane fuel cells (PEMFC) was established by Monte Carlo method. The model takes into account all the four components in a typical PEMFC catalyst layer: platinum (Pt), carbon, ionomer and pore. The elemental voxels in the lattice were set fine enough so that each average sized Pt particulate in Pt/C catalyst can be represented. Catalyst utilization in the modeled catalyst layer was calculated by counting up the number of facets of Pt voxels where “three phase contact” are met. The effects of some factors, including porosity, ionomer content, Pt/C particle size and Pt weight percentage in the Pt/C catalyst, on catalyst utilization were investigated and discussed.

关键词： catalyst layer PEM fuel cell lattice model Monte Carlo method catalyst utilization